| 3-Methoxyacetophenone Basic information |
| Product Name: |
3-Methoxyacetophenone |
| Synonyms: |
3-ACETYLANISOLE;1-(3-methoxyphenyl)ethanone;3'-METHOXYACETOPHENONE;3-METHOXYACETOPHENONE;M-ACETYLANISOLE;M-ACETANISOLE;3'-Methoxyacetophenone m-Acetanisole 3-Acetanisole;3-Methoxyacetophenone,>99% |
| CAS: |
586-37-8 |
| MF: |
C9H10O2 |
| MW: |
150.17 |
| EINECS: |
209-573-3 |
| Product Categories: |
Aromatic Acetophenones & Derivatives (substituted);bc0001 |
| Mol File: |
586-37-8.mol |
 |
| |
| 3-Methoxyacetophenone Chemical Properties |
| Melting point |
-7 °C |
| Boiling point |
239-241 °C(lit.) |
| density |
1.094 g/mL at 25 °C(lit.) |
| vapor pressure |
2.41-10.665Pa at 20-25℃ |
| refractive index |
n20/D 1.542(lit.) |
| Fp |
>230 °F |
| storage temp. |
Keep in dark place,Sealed in dry,Room Temperature |
| solubility |
Chloroform (Slightly), Ethyl Acetate (Slightly) |
| form |
Liquid |
| Specific Gravity |
1.094 |
| color |
Clear slightly yellow to slightly brown |
| Water Solubility |
Fully miscible in water. Soluble in alcohol. |
| Sensitive |
Light Sensitive |
| BRN |
878552 |
| LogP |
1.86-2.085 at 20-25℃ |
| CAS DataBase Reference |
586-37-8(CAS DataBase Reference) |
| NIST Chemistry Reference |
Ethanone, 1-(3-methoxyphenyl)-(586-37-8) |
| Hazard Codes |
Xn,Xi |
| Risk Statements |
36/38-22-36/37/38 |
| Safety Statements |
23-24/25-37/39-26-36 |
| WGK Germany |
3 |
| Hazard Note |
Irritant |
| HS Code |
29145000 |
| Provider |
Language |
| m-Methoxyacetophenone |
English |
| ACROS |
English |
| SigmaAldrich |
English |
| ALFA |
English |
| |
| 3-Methoxyacetophenone Usage And Synthesis |
| Chemical Properties |
clear slightly yellow to slightly brown liquid |
| Uses |
It is applied in the asymmetric transfer hydrogenation of ketones catalyzed by ruthenium(II) complexes. |
| Synthesis Reference(s) |
Journal of the American Chemical Society, 109, p. 7137, 1987 DOI: 10.1021/ja00257a038
Synthesis, p. 406, 1987 DOI: 10.1055/s-1987-27965 |
| Flammability and Explosibility |
Non flammable |
| |
| 3-Methoxyacetophenone Preparation Products And Raw materials |
| Raw materials |
Benzene, 1-methoxy-3-(1-methylethenyl)--->3-Methoxyphenylboronic acid-->3-ETHYNYLANISOLE 96-->3'-METHOXYPHENACYL BROMIDE-->Acetovanillone-->3-Bromoanisole |
| Preparation Products |
2-Phenylbenzoxazole-->2'-Hydroxy-5'-methoxyacetophenone-->2-(3-METHOXYPHENYL)QUINOLINE-4-CARBOXYLIC ACID-->3'-METHOXY-3-(4-METHYLPHENYL)PROPIOPHENONE-->5-(3-METHOXYPHENYL)-5-METHYLIMIDAZOLIDINE-2,4-DIONE-->(2E)-1-(3-methoxyphenyl)-3-(thiophen-2-yl)prop-2-en-1-one-->2-(3-METHOXYPHENYL)-8-METHYLQUINOLINE-4-CARBOXYLIC ACID |
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