Bis(4-fluorophenyl)-methanone

Bis(4-fluorophenyl)-methanone

Product Introduction

Bis(4-fluorophenyl)-methanone Basic information
Product Name: Bis(4-fluorophenyl)-methanone
Synonyms: 4,4'-difluoro-benzophenon;4,4'-DIFLUOROBENZOPHENONE;4,4-DIFLUOROBENZOPHENONE;Benzophenone, 4,4'-difluoro-;bis(4-fluorophenyl)-methanon;Bis(p-fluorophenyl) ketone;bis(p-fluorophenyl)ketone;Di-p-fluorophenyl ketone
CAS: 345-92-6
MF: C13H8F2O
MW: 218.2
EINECS: 206-466-3
Product Categories: C13 to C14;Carbonyl Compounds;Benzophenones (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research;Ketones;Fluorobenzene Series;FINE Chemical & INTERMEDIATES;Aromatic Benzophenones & Derivatives (substituted);Pharmaceutical raw materials;345-92-6
Mol File: 345-92-6.mol
Bis(4-fluorophenyl)-methanone Structure
 
Bis(4-fluorophenyl)-methanone Chemical Properties
Melting point 102-105 °C (lit.)
Boiling point 137°C (3 torr)
density 1.2543 (estimate)
vapor pressure 0.005Pa at 20℃
Fp 170-172°C/10mm
storage temp. Sealed in dry,Room Temperature
solubility Insoluble in water
form Crystalline Powder
color White to slightly yellow
Water Solubility 8.757mg/L at 20℃
BRN 516231
InChIKey LSQARZALBDFYQZ-UHFFFAOYSA-N
LogP 3.37 at 20℃
CAS DataBase Reference 345-92-6(CAS DataBase Reference)
NIST Chemistry Reference 4,4'-Difluorobenzophenone(345-92-6)
EPA Substance Registry System 4,4'-Difluorobenzophenone (345-92-6)
 
Safety Information
Hazard Codes Xi,N,Xn
Risk Statements 36/37/38-51/53-22
Safety Statements 26-37/39-36-61
RIDADR UN 3077 9 / PGIII
WGK Germany 3
RTECS DJ0685000
HazardClass IRRITANT
HS Code 29143990
 
MSDS Information
Provider Language
Bis(4-fluorophenyl)-methanone English
ACROS English
SigmaAldrich English
ALFA English
 
Bis(4-fluorophenyl)-methanone Usage And Synthesis
Chemical Properties white to slightly yellow crystalline powder
Uses 4,4′-Difluorobenzophenone has been used in the study of thermal stability, water uptake and proton conductivity of carboxylated, carboxylated/sulfonated, and crosslinked membranes.
Synthesis Reference(s) Journal of the American Chemical Society, 90, p. 540, 1968 DOI: 10.1021/ja01004a087
General Description 4,4′-Difluorobenzophenone is typically used as a starting material for the preparation of polyetheretherketone (PEEK) polymer, a high-temperature thermoplastic, which finds wide use in dentistry as well as in automotive, oil industries, etc.
 
Bis(4-fluorophenyl)-methanone Preparation Products And Raw materials
Raw materials Fluorobenzene-->(2-Naphtyl)tributylstannane-->4-FLUORO-(TRI-N-BUTYLSTANNYL)BENZENE-->4,4'-Difluorodiphenylmethane-->4,4'-Difluorobenzhydrol-->4,4'-Dichlorobenzophenone-->4-Fluorobenzoyl chloride-->Dimethyl sulfone-->4-FLUOROBENZENEDIAZONIUM TETRAFLUOROBORATE-->4-Fluorobenzaldehyde
Preparation Products (4-(4-[BIS(4-FLUOROPHENYL)METHYL]PIPERAZIN-1-YL)PHENYL)METHANOL-->1,1'-(4-CHLOROBUTYLIDENE)BIS(4-FLUOROBENZENE)-->4-FLUORO-4'-NITROBENZOPHENONE-->BIS-(4-FLUORO-PHENYL)-PHENYL-METHANOL-->1,1-BIS(4-FLUOROPHENYL)-1-BUTENE

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