2,2-Bis(bromomethyl)propane-1,3-diol

2,2-Bis(bromomethyl)propane-1,3-diol

Product Introduction

2,2-Bis(bromomethyl)propane-1,3-diol Basic information
Uses
Product Name: 2,2-Bis(bromomethyl)propane-1,3-diol
Synonyms: Pentaerythritol dibromide;Pentaerythritol dibromohydrin;pentaerythritoldibromide;pentaerythritoldibromohydrin;SAYTEX(R) FR-1138 FLAME RETARDANT;SAYTEX FR-1138;2,2-DI(BROMOMETHYL)PROPANE-1,3-DIOL;2,2-BIS(BROMOMETHYL)-1,3-PROPANEDIOL
CAS: 3296-90-0
MF: C5H10Br2O2
MW: 261.94
EINECS: 221-967-7
Product Categories: Aliphatics;Mutagenesis Research Chemicals;Pharmaceutical Intermediates;Organics;Alcohols;Monomers;Polymer Science;bc0001;3296-90-0
Mol File: 3296-90-0.mol
2,2-Bis(bromomethyl)propane-1,3-diol Structure
 
2,2-Bis(bromomethyl)propane-1,3-diol Chemical Properties
Melting point 112-114 °C(lit.)
Boiling point 235°C (rough estimate)
density 1.8049 (rough estimate)
vapor pressure 10 mm Hg ( 178 °C)
refractive index 1.5120 (estimate)
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly, Heated), Methanol (Slightly, Heated)
form Solid
pka 13.57±0.10(Predicted)
color White to Off-White
Water Solubility 19.4g/L at 20℃
LogP 1.08
CAS DataBase Reference 3296-90-0(CAS DataBase Reference)
IARC 2B (Vol. 77) 2000
NIST Chemistry Reference 1,3-Propanediol, 2,2-bis(bromomethyl)(3296-90-0)
EPA Substance Registry System 2,2-Bis(bromomethyl)-1,3-propanediol (3296-90-0)
 
Safety Information
Hazard Codes T,Xn
Risk Statements 45-36/37/38-40-22
Safety Statements 53-23-26-36/37/39-45-36/37
RIDADR 2811
WGK Germany 3
RTECS TY3195500
HS Code 29055900
Hazardous Substances Data 3296-90-0(Hazardous Substances Data)
 
MSDS Information
Provider Language
2,2-Bis(bromomethyl)-1,3-propanediol English
SigmaAldrich English
 
2,2-Bis(bromomethyl)propane-1,3-diol Usage And Synthesis
Uses It is a brominated flame retardant, previously shown to be a multisite carcinogen in experimental animals. The compound is used as a fire retardant in unsaturated polyester resins, in molded products, and in rigid polyurethane foam. It shows clear evidence of carcinogenicity and genotoxicity activity.
Chemical Properties Solid
Uses It is a brominated flame retardant, previously shown to be a multisite carcinogen in experimental animals. The compound is used as a fire retardant in unsaturated polyester resins, in molded products, and in rigid polyurethane foam. It shows clear evidence of carcinogenicity and genotoxicity activity.
Definition ChEBI: 2,2-Bis(bromomethyl)propane-1,3-diol is a primary alcohol.
General Description Off-white powder.
Air & Water Reactions Hygroscopic . Insoluble in water.
Reactivity Profile A brominated alcohol. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.
Fire Hazard Literature sources indicate that 2,2-Bis(bromomethyl)propane-1,3-diol is nonflammable.
Carcinogenicity The flame retardant 2,2-bis(bromomethyl)-1,3-propanediol, technical grade, is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
 
2,2-Bis(bromomethyl)propane-1,3-diol Preparation Products And Raw materials
Raw materials Pentaerythritol
Preparation Products ZENIPLATIN-->701209-98-5-->1,3-Dioxane, 5,5-bis(broMoMethyl)-2-phenyl-

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