Products

2-Allyloxyethanol

Product Introduction

2-Allyloxyethanol Basic information

Odor

Product Name:	2-Allyloxyethanol
Synonyms:	2-(2-propenyloxy)-ethano;2-Prop-2-enoxyethanol;2-Allyloxyethyl alcohol;2-Allyloxyethanol,Ethylene glycol allyl ether;Allyl Glycol 2-Allyloxyethanol;Ethylene glycol monallyl ether;EGMAE;2-Allyloxyethanole
CAS:	111-45-5
MF:	C5H10O2
MW:	102.13
EINECS:	203-871-7
Product Categories:	ester series;Ethylene Glycols & Monofunctional Ethylene Glycols;Monofunctional Ethylene Glycols
Mol File:	111-45-5.mol

2-Allyloxyethanol Chemical Properties

Boiling point	159 °C(lit.)
density	0.955 g/mL at 25 °C(lit.)
vapor pressure	1.842hPa at 25℃
refractive index	n20/D 1.436(lit.)
Fp	150 °F
storage temp.	2-8°C
solubility	Completely miscible in water
form	clear liquid
pka	14.50±0.10(Predicted)
Specific Gravity	0.955
color	Colorless to Almost colorless
Odor	mild mushroom
Water Solubility	454g/L at 25℃
InChIKey	GCYHRYNSUGLLMA-UHFFFAOYSA-N
LogP	-0.12 at 20℃
CAS DataBase Reference	111-45-5(CAS DataBase Reference)
NIST Chemistry Reference	Ethanol, 2-(2-propenyloxy)-(111-45-5)
EPA Substance Registry System	Ethanol, 2-(2-propenyloxy)- (111-45-5)

Safety Information

MSDS Information

Provider	Language
2-Allyloxyethanol	English
SigmaAldrich	English

2-Allyloxyethanol Usage And Synthesis

Odor	Peculiar, earthy, mushroom-like odor. The odor of this ether is too weak and too rarely wanted that this material can become popular. it will probably remain a rare item on the research shelf.
Chemical Properties	Colorless transparent liquid
Uses	2-allyloxyethanol could synthesize a new ester (Las9) with lasalocid. Las9 could form complexes with LiC, NaC, KC, RbC, and CsC cations. 2-allyloxyethanol could be used as an end-capping reagent to synthesize 2-allyloxyethanol-terminated polyurethane which is a modifier of polyurethane-modified polydimethylsiloxane (PUMS) coating[1-2].
Preparation	2-allyloxyethanol is produced from Allyl alcohol and Ethylene under pressure and in the presence of a catalyst.
Flammability and Explosibility	Flammable
Solubility in organics	Soluble in alcohol and oils.
References	[1] Rados?aw Pankiewicz, Bogumil Brzezinski, Grzegorz Schroeder. "Spectroscopic and PM5 semiempirical study of a new lasalocid ester with 2-allyloxyethanol and its complexes with monovalent cations." Journal of Molecular Structure 789 1 (2006): Pages 1-7. [2] Zhe Sun . "Polyurethane covalently modified polydimethylsiloxane (PDMS) coating with increased surface energy and re-coatability." Progress in Organic Coatings 146 (2020): Article 105744.