2-Hydroxy-1-naphthaldehyde

2-Hydroxy-1-naphthaldehyde

Product Introduction

2-Hydroxy-1-naphthaldehyde Basic information
Product Name: 2-Hydroxy-1-naphthaldehyde
Synonyms: 2-Hydroxy-1-phthaldehyde;1-formyl-2-hydroxynaphthalene;1-Formyl-2-hydroxy-naphthalene;1-Formyl-2-naphthol;1-Hydroxy-2-naphthalenecarboxaldehyde;1-Naphthaldehyde, 2-hydroxy-;2-Hydroxy-1-naphthalaldehyde;2-hydroxy-1-naphthaldehyd
CAS: 708-06-5
MF: C11H8O2
MW: 172.18
EINECS: 211-902-0
Product Categories: Naphthalene series;Building Blocks;C10-C12;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Intermediates of Dyes and Pigments;Aromatic Aldehydes & Derivatives (substituted);Aldehydes;C10 to C21;Carbonyl Compounds
Mol File: 708-06-5.mol
2-Hydroxy-1-naphthaldehyde Structure
 
2-Hydroxy-1-naphthaldehyde Chemical Properties
Melting point 76-80 °C (lit.)
Boiling point 192 °C/27 mmHg (lit.)
density 1.1153 (rough estimate)
vapor pressure 0.002Pa at 20℃
refractive index 1.5500 (estimate)
Fp 191-193°C/27mm
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform, Methanol
form Crystalline Moist Powder
pka 8.27±0.50(Predicted)
color Yellow
Water Solubility Soluble in water (40 g/L at 20°C).
Sensitive Air Sensitive
BRN 742777
LogP 6 at 23℃ and pH8
CAS DataBase Reference 708-06-5(CAS DataBase Reference)
NIST Chemistry Reference 1-Naphthalenecarboxaldehyde, 2-hydroxy-(708-06-5)
EPA Substance Registry System 1-Naphthalenecarboxaldehyde, 2-hydroxy- (708-06-5)
 
Safety Information
Hazard Codes Xi,N
Risk Statements 36/37/38-50/53
Safety Statements 26-36-60-61-24/25-37
RIDADR UN 3077 9/PG 3
WGK Germany 2
RTECS QJ0300000
TSCA Yes
HazardClass 9
HS Code 29124990
 
MSDS Information
Provider Language
ACROS English
SigmaAldrich English
ALFA English
 
2-Hydroxy-1-naphthaldehyde Usage And Synthesis
Chemical Properties Powder
Uses 2-Hydroxy-1-naphthaldehyde is used in Merrified-type synthesis to deterime free amino acid groups in polymers.
Definition ChEBI: 2-hydroxy-1-naphthaldehyde is a member of the class of naphthaldehydes that is naphthalene-1-carbaldehyde substituted by a hydroxy group at position 2. Active core of sirtinol (CHEBI:73158). It is a member of naphthaldehydes and a member of naphthols.
Purification Methods Crystallise the aldehyde from EtOH (1.5mL/g), aqueous EtOH, aqueous AcOH (m 84o), EtOAc or H2O. [Russell & Lockhart Org Synth Coll Vol III 463 1955, Beilstein 8 H 143, 8 I 564, 8 II 171, 8 III 1108, 8 IV 1160.]
 
2-Hydroxy-1-naphthaldehyde Preparation Products And Raw materials
Raw materials Polyvinyl chloride-->VINYLACETIC ACID-->cellulore-->Beryllium-->1-(1-pyrrolidinylmethyl)-2-naphthol-->1-Naphthalenecarboxaldehyde,2-hydroxy-, 2-(2,4-dinitrophenyl)hydrazone
Preparation Products fluorescent whitening agent OM-->fluorescent whitenin agent ACF-->1-HYDROXY-2-NAPHTHALDEHYDE-->N,N'-DISALICYLAL-1,2-PHENYLENEDIAMINE-->METHYL 2-HYDROXY-1-NAPHTHOATE-->2-ACETYL-BENZO[F]CHROMEN-3-ONE-->2-(benzo[d]thiazol-2-yl)-3H-benzo[f]chromen-3-one-->2-(2-PROPYNYLOXY)-1-NAPHTHALDEHYDE

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