Product Introduction
| 2,4,6-Tribromophenol Basic information |
| Product Name: | 2,4,6-Tribromophenol |
| Synonyms: | 2,4,6-TRIBROMOPHENOL;BROMOL;2,4,6-TRIBROMOPHENOL, 1X1ML, CH2CL2, 200 0UG/ML;2,4,6-TRIBROMOPHENOL, 1000MG, NEAT;2,4,6-TRIBROMOPHENOL, 1X1ML, MEOH, 2000U G/ML;2,4,6-TRIBROMOPHENOL OEKANAL, 250 MG;2,4,6-Tribromophenol98%;Phenol, 2,4,6-tribromo- |
| CAS: | 118-79-6 |
| MF: | C6H3Br3O |
| MW: | 330.8 |
| EINECS: | 204-278-6 |
| Product Categories: | Organic Building Blocks;Oxygen Compounds;Halogenated;Analytical Standards;AromaticsChemical Class;Phenols;BromoAnalytical Standards;PhenolsVolatiles/ Semivolatiles;T-ZAlphabetic;Alpha Sort;Chemical Class;TP - TZ;Antiseptic & germicide;Flame retardant. It is mainly used in epoxy resin and polyurethane plastics etc.;Industrial/Fine Chemicals |
| Mol File: | 118-79-6.mol |
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| 2,4,6-Tribromophenol Chemical Properties |
| Melting point | 90-94 °C(lit.) |
| Boiling point | 282-290 °C746 mm Hg(lit.) |
| density | 2.55 |
| vapor density | 11.4 (vs air) |
| vapor pressure | 0.042-0.063Pa at 25℃ |
| refractive index | 1.5580 (estimate) |
| Fp | 282-290°C subl. |
| storage temp. | 2-8°C |
| solubility | water: soluble0.007g/100ml at 25°C |
| pka | 6.34±0.23(Predicted) |
| form | Powder |
| color | White to slightly brown |
| Water Solubility | 71 mg/L (15 ºC) |
| Merck | 14,9613 |
| BRN | 776920 |
| LogP | 3.7-3.89 at 23.5-25℃ |
| CAS DataBase Reference | 118-79-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Phenol, 2,4,6-tribromo-(118-79-6) |
| EPA Substance Registry System | 2,4,6-Tribromophenol (118-79-6) |
| Safety Information |
| Hazard Codes | Xi,N,Xn,T,F |
| Risk Statements | 36/37/38-51/53-20/22-39/23/24/25-23/24/25-11-63-43-45-50-36-67-40-22 |
| Safety Statements | 26-36-61-37/39-45-36/37-16-7-24/25-23-53-37 |
| RIDADR | UN 1230 3/PG 2 |
| WGK Germany | 2 |
| RTECS | SN1225000 |
| TSCA | Yes |
| HazardClass | 9 |
| PackingGroup | III |
| HS Code | 29081990 |
| Hazardous Substances Data | 118-79-6(Hazardous Substances Data) |
| Toxicity | guinea pig,LDLo,oral,3gm/kg (3000mg/kg),National Technical Information Service. Vol. OTS0522208, |
| MSDS Information |
| Provider | Language |
|---|---|
| 2,4,6-Tribromophenol | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| 2,4,6-Tribromophenol Usage And Synthesis |
| Chemical Properties | 2,4,6-Tribromophenol is a white needle-shaped into prismatic crystals with has a penetrating bromine odor. In alcohol, chloroform, ether and caustic alkali solution, almost insoluble in water, sweet taste. |
| Uses | 2,4,6-Tribromophenol is used as a certified reference standard for the determination of the analyte in multiple solid formulation drug products using gas chromatography coupled to tandem mass spectrometry. |
| Uses | 2,4,6-Tribromophenol was used in analysis of nonylphenol, nonylphenol monoethoxylate and octylphenol in sediment, water and fish tissue. |
| Definition | ChEBI: 2,4,6-tribromophenol is a bromophenol that is phenol in which the hydrogens at positions 2, 4 and 6 have been replaced by bromines. It is commonly used as a fungicide and in the preparation of flame retardants. It has a role as an environmental contaminant, a fungicide and a marine metabolite. |
| Production Methods | 2,4,6-Tribromophenol is produced by the controlled bromination of phenol. |
| General Description | Soft, long, white crystals with a bromine odor. |
| Air & Water Reactions | Slightly soluble in water. |
| Reactivity Profile | 2,4,6-Tribromophenol can react with oxidizing materials . |
| Hazard | By ingestion, inhalation, skin absorption. Strong skin irritant. |
| Fire Hazard | Data is not available for 2,4,6-Tribromophenol. 2,4,6-Tribromophenol is probably non-flammable. |
| Flammability and Explosibility | Non flammable |
| Purification Methods | Crystallise the phenol from EtOH or pet ether. Dry it under vacuum over P2O5 at room temperature. [Beilstein 6 IV 1067.] |
| 2,4,6-Tribromophenol Preparation Products And Raw materials |
| Raw materials | 2-(2,4,6-tribromophenoxy)acetic acid-->2,6-Dibromophenol-->2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE-->4-Bromophenol |
| Preparation Products | 4-AMINO-3-METHOXYPHENYLBORONIC ACID, PINACOL ESTER-->2,4-Dibromophenol-->2-Allyloxy-1,3,5-tribromobenzene-->2,4,6-TRIBROMOANISOLE-->2,4,6-TRIBROMOPHENOLSODIUMSALT-->1,2-Bis(2,4,6-tribromophenoxy)ethane-->bis(2,4,6-tribromophenyl) fumarate-->2,4,6-Tribromophenyl Sulfate Potassium Salt-->2,4,6-TRIBROMOPHENYL ACETATE |
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