2-ETHYL-2-HEXENAL

2-ETHYL-2-HEXENAL

Product Introduction

2-ETHYL-2-HEXENAL Basic information
Product Name: 2-ETHYL-2-HEXENAL
Synonyms: 2-ETHYL-3-PROPYLACROLEIN;2-ETHYL-2-HEXEN-1-AL;2-ETHYL-2-HEXENAL;TIMTEC-BB SBB008156;TRANS-2-ETHYL-2-HEXENAL;(2E)-2-Ethyl-2-hexenal;2-ethyl-2-hexanal;2-ethyl-2-hexena
CAS: 645-62-5
MF: C8H14O
MW: 126.2
EINECS: 211-448-3
Product Categories: 1
Mol File: 645-62-5.mol
2-ETHYL-2-HEXENAL Structure

 

2-ETHYL-2-HEXENAL Chemical Properties
Melting point 3.5°C (estimate)
Boiling point 175°C(lit.)
density 0,85 g/cm3
refractive index 1.4490 to 1.4530
FEMA 4612 | 2-ETHYL-2-HEXENAL
Fp 68°C
storage temp. Inert atmosphere,Store in freezer, under -20°C
Odor powerful odor
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
LogP 2.66
EPA Substance Registry System 2-Ethyl-2-hexenal (645-62-5)

 

Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
RIDADR 1760
RTECS MP6300000
Hazardous Substances Data 645-62-5(Hazardous Substances Data)

 

 
2-ETHYL-2-HEXENAL Usage And Synthesis
Chemical Properties colourless liquid with a strong smell
Chemical Properties 2-Ethyl-3-propyl acrolein is a colorless or yellowish liquid with a sharp, powerful, irritating odor
Uses Insecticide, organic synthesis (intermediate), warning agents, and leak detectors.
Definition ChEBI: 2-ethyl-2-hexenal is a monounsaturated fatty aldehyde that is hex-2-enal substituted by an ethyl group at position 2. It has a role as a plant metabolite, a human metabolite and a flavouring agent. It is a monounsaturated fatty aldehyde and an enal.
Synthesis Reference(s) Tetrahedron Letters, 15, p. 959, 1974 DOI: 10.1016/S0040-4039(01)82378-9
General Description Yellow liquid. Floats on water.
Air & Water Reactions Insoluble in water.
Reactivity Profile 2-ETHYL-2-HEXENAL is an aldehyde. Aldehydes are frequently involved in self-condensation or polymerization reactions. These reactions are exothermic; they are often catalyzed by acid. Aldehydes are readily oxidized to give carboxylic acids. Flammable and/or toxic gases are generated by the combination of aldehydes with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Aldehydes can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation. 2-ETHYL-2-HEXENAL will react with oxidants.
Hazard Toxic by inhalation and ingestion; strong irritant.
Health Hazard Vapor is irritating. Contact produces skin and eye irritation.
Flammability and Explosibility Not classified
Potential Exposure Those workers involved in organic synthesis operations and use of this flammable and toxic aldehyde warning agent.v
Shipping UN1988 Aldehydes, flammable, toxic, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 6.1-Poisonous materials, Technical Name Required
Incompatibilities Aldehydes are frequently involved in self-condensation or polymerization reactions. These reactions are exothermic; they are often catalyzed by acid. Aldehydes are readily oxidized to give carboxylic acids. Flammable and/or toxic gases are generated by the combination of aldehydes with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Aldehydes can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, caustics, ammonia, and amines
Waste Disposal Incineration, or dissolve in flammable solvent and spray into incinerator containing afterburner

 

2-ETHYL-2-HEXENAL Preparation Products And Raw materials
Raw materials 2-Heptenal, 2-ethyl--->2-Hexenal, 2-propyl--->alpha-ethylcinnamaldehyde-->2-ethyl-3-hydroxyhexanal-->1,1-Bis(p-anisyl)ethene-->2-PROPYL-2-HEPTENAL-->Benzaldehyde-->1-Butanol
Preparation Products 2-Ethylhexanoic acid-->2-ETHYLHEXANAL-->5-Ethyl-2-methylpyridine-->2-ETHYLCROTONALDEHYDE-->hex-2-enal-->2-Ethylhexylamine

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