Product Introduction
| Sodium dicyanamide Basic information |
| Product Name: | Sodium dicyanamide |
| Synonyms: | CyanaMide, N-cyano-,sodiuM salt (1:1);SodiuM dicyanaMide (DCD sodiuM);Sodium dicyamide;SodiuM DicyanaMide, 97+%;SODIUM DICYANAMIDE;SODIUM DICYANOAMIDE;NADCA;DICYANAMIDE,SODIUM SALT |
| CAS: | 1934-75-4 |
| MF: | C2N3Na |
| MW: | 89.03 |
| EINECS: | 217-703-5 |
| Product Categories: | Pyridines;Hydrocyanic acid derivatives;C-X Bond Formation (Non-Halogen);Others;Synthetic Reagents;Various hydrocyanic acid derivatives |
| Mol File: | 1934-75-4.mol |
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| Sodium dicyanamide Chemical Properties |
| Melting point | 300 °C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Methanol (sparingly), Water |
| form | Solid |
| color | White |
| Water Solubility | 260 g/L (30 ºC) |
| Sensitive | Hygroscopic |
| BRN | 3913818 |
| InChI | InChI=1S/C2N3.Na/c3-1-5-2-4;/q-1;+1 |
| InChIKey | IXBPPZBJIFNGJJ-UHFFFAOYSA-N |
| SMILES | N([Na])(C#N)C#N |
| LogP | 0.433 (est) |
| EPA Substance Registry System | Cyanamide, cyano-, sodium salt (1934-75-4) |
| Safety Information |
| Hazard Codes | Xn,Xi |
| Risk Statements | 22-36/37/38 |
| Safety Statements | 26-36-37/39 |
| RIDADR | UN 3077 |
| WGK Germany | 1 |
| F | 3 |
| Hazard Note | Irritant |
| TSCA | Yes |
| HS Code | 29269090 |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| Sodium dicyanamide Usage And Synthesis |
| Chemical Properties | White to off-white powder |
| Uses | Sodium dicyanamide is used or the production of pharmaceuticals (e.g. chlorhexidine, biguanide, proguanil and alexidine). Product Data Sheet |
| Uses | Reactant for preparation of:
Nickel diacetylpyridine dioximate pentanuclear, octanuclear and decanuclear cluster complexes Decanuclear manganese(II/III) oxo azide diolate clusters as supertetrahedral building-blocks to design extended magnetic networks Ruthenium bipyridine complexes entrapped in iron and manganese dicyanamide two-dimensional anionic sheet-like coordination polymeric networks exhibiting dual emission photoluminescence Lead dicyanamide-bridged nitronyl nitroxide radical polymeric complex Antiferromagnetically coupled hexanuclear copper(II) Schiff base complexes with dicyanamido bridges CuII2L based polymeric ladders using dicyanamide bridges Luminous hexacoordinated coordination polymers of cadmium(II), containing dicyanamide bridges |
| General Description | Sodium dicyanamide (NaDCA) is a white to off-white powder.It was used as a leaching reagent for gold recovery and can form a new catalyst system for benzene liquid hydrogenation to cyclohexene[1-2]. |
| References | [1] Li G, et al. Gold-leaching performance and mechanism of sodium dicyanamide. International Journal of Minerals, Metallurgy and Materials, 2021; 28: 1759–1768. [2] Schwab F, et al. Simple selective hydrogenation of benzene to cyclohexene in the presence of sodium dicyanamide. Green Chemistry, 2013; 15: 646-649. |
| Sodium dicyanamide Preparation Products And Raw materials |
| Preparation Products | 1-ETHYL-3-METHYLIMIDAZOLIUM DICYANAMIDE-->2,4-Dichloro-1,3,5-triazine-->N,N-Bis[1(2)H-tetrazol-5-yl]amine-->2,4-Dichloro-6-methyl-1,3,5-triazine-->Dithiobiuret-->1,6-Bis(cyano-guanidino)hexane-->1,2,4-oxadiazole-3,5-diaMine-->2,2,4,6-tetrachloro-2,2-dihydro-1,3,5,2-triazaphosphorine-->1H-Pyrazole-1-carboximidamide, N'-cyano-, [C(E)]--->OLANEXIDINE intermediate-->N-cyano-N'-methylguanidine-->N-Cyano-1-chloroforMaMidine |
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