Trimethylolpropane Tris(3-mercaptopropionate)

Trimethylolpropane Tris(3-mercaptopropionate)

Product Introduction

Trimethylolpropane Tris(3-mercaptopropionate) Basic information
Product Name: Trimethylolpropane Tris(3-mercaptopropionate)
Synonyms: p33ING1b;p47;p47ING1a;Propanoic acid,3-mercapto-, 1,1'-[2-ethyl-2-[(3-mercapto-1-oxopropoxy)methyl]-1,3-propanediyl]ester;opanediylester;propanoicacid,3-mercapto-,2-ethyl-2-[(3-mercapto-1-oxopropoxy)methyl]-1,3-pr;2-ethyl-2-[(3-mercapto-1-oxopropoxy)methyl]propane-1,3-diyl bis[3-mercaptopropionate];PROPANOIC ACID, 3-MERCAPTO-, 2-ETHYL-2- [(3-MERCAPTO-1-OXOPROPOXY) METHYL]-1, 3-PROPANEDIYL ESTER
CAS: 33007-83-9
MF: C15H26O6S3
MW: 398.56
EINECS: 251-336-1
Product Categories: Self-Assembly Materials;Sulfur Compounds;Thiols/Mercaptans;ThiolsOrganic Building Blocks;Chain Transfer Agents;Building Blocks;Self Assembly&Contact Printing;Chemical Synthesis;Materials Science;Organic Building Blocks;Polymer Additives;Polymer Science;Sulfur Compounds
Mol File: 33007-83-9.mol
Trimethylolpropane Tris(3-mercaptopropionate) Structure
 
Trimethylolpropane Tris(3-mercaptopropionate) Chemical Properties
Boiling point 220 °C0.3 mm Hg(lit.)
density 1.21 g/mL at 25 °C(lit.)
vapor pressure 0Pa at 25℃
refractive index n20/D 1.518(lit.)
Fp 205 °F
storage temp. -70°C
pka 9.14±0.10(Predicted)
form clear liquid
color Colorless to Almost colorless
Specific Gravity 1.2 (30℃)1.210
Water Solubility 320mg/L at 20℃
InChI InChI=1S/C15H26O6S3/c1-2-15(9-19-12(16)3-6-22,10-20-13(17)4-7-23)11-21-14(18)5-8-24/h22-24H,2-11H2,1H3
InChIKey IMQFZQVZKBIPCQ-UHFFFAOYSA-N
SMILES C(OC(=O)CCS)C(CC)(COC(=O)CCS)COC(=O)CCS
LogP 2.8 at 20℃
EPA Substance Registry System 3-Mercaptopropionic acid triester with trimethylolpropane (33007-83-9)
 
Safety Information
Hazard Codes Xi,T
Risk Statements 36/37/38-61
Safety Statements 26-37/39-45-53
RIDADR UN 3334
WGK Germany 3
HS Code 29309090
 
MSDS Information
Provider Language
SigmaAldrich English
 
Trimethylolpropane Tris(3-mercaptopropionate) Usage And Synthesis
Description Trimethylolpropane tris(3-mercaptopropionate) is a colorless crystalline compound that dissolves in water and polar solvents but remains insoluble in nonpolar solutions. It is a crucial cross-linking agent in the formulation of polymers, resins, and coatings and is used as a photoinitiator for UV-reactive coatings and inks. Additionally, Trimethylolpropane tris(3-mercaptopropionate) acts as a chelating agent in the treatment of heavy metal toxicity, and it is used to modify high internal phase emulsions to extract heavy metals from water.
Chemical Properties Colorless to light yellow liquid
Uses Trimethylolpropane tris(3-Mercaptopropanoate) can be used to prepare UV curing environmentally friendly nail polish.
Uses Trimethylolpropane tris(3-mercaptopropionate) may be used in the following studies:

Preparation of hydrogels, via crosslinking inulin derivatives.

Construction of porous hybrid monolithic materials.

As monomer for the preparation of a new thiol-ene based polymeric fluorescence sensor, via photo initiated polymerization.

General Description Trimethylolpropane tris(3-mercaptopropionate) is reported as a multi-thiol crosslinking reagent.
Synthesis Sequentially adding cyclohexane, trimethylolpropane, 3-mercaptopropionic acid, and p-toluenesulfonic acid into a reaction container and reacting in an oil bath; washing the product by adopting heating reflux and cooling; drying to obtain a crude product; and finally, performing reduced pressure distillation and filtration, thereby obtaining trimethylolpropane tris(3-mercaptopropionate).
 
Trimethylolpropane Tris(3-mercaptopropionate) Preparation Products And Raw materials
Raw materials 3-Mercaptopropionic acid-->Trimethylolpropane

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