4,4'-Dichlorodiphenyl Sulfone

4,4'-Dichlorodiphenyl Sulfone

Product Introduction

4,4'-Dichlorodiphenyl sulfone Basic information
Product Name: 4,4'-Dichlorodiphenyl sulfone
Synonyms: 1,1'-sulfonylbis[4-chloro-benzene];4,4'-Dichlorophenyl sulfone;Benzene, 1,1'-sulfonylbis*4-chloro-;Benzene, 1,1'-sulfonylbis[4-chloro-;di-p-chlorophenylsulfone;p,p'-dichlorodiphenylsulfone;p,p'-Dichlorodiphenyl sulfone;p-Chlorophenyl sulfone
CAS: 80-07-9
MF: C12H8Cl2O2S
MW: 287.16
EINECS: 201-247-9
Product Categories: Imidazoles;Organics;Sulphur Derivatives;Diphenyl Sulfones (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research;bc0001
Mol File: 80-07-9.mol
4,4'-Dichlorodiphenyl sulfone Structure
 
4,4'-Dichlorodiphenyl sulfone Chemical Properties
Melting point 143-146 °C(lit.)
Boiling point 250 °C10 mm Hg(lit.)
density 1.54g/cm3
vapor pressure 0Pa at 25℃
Fp 233 °C
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Fine Powder
color White
Water Solubility <0.1 g/100 mL at 20 ºC
Sensitive Moisture Sensitive
BRN 2052955
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
LogP 3.9 at 20℃
CAS DataBase Reference 80-07-9(CAS DataBase Reference)
NIST Chemistry Reference 4,4'-Dichlorodiphenyl sulphone(80-07-9)
EPA Substance Registry System p,p'-Dichlorodiphenyl sulfone (80-07-9)
 
Safety Information
Hazard Codes Xi,C
Risk Statements 36/37/38
Safety Statements 22-24/25-37/39-26
WGK Germany 2
RTECS WR3450000
Hazard Note Harmful/Corrosive/Moisture Sensitive
TSCA Yes
HS Code 29309070
Hazardous Substances Data 80-07-9(Hazardous Substances Data)
Toxicity LD50 orl-mus: 24 g/kg HCACAV 29,1317,46
 
MSDS Information
Provider Language
Bis(4-chlorophenyl) sulfone English
ACROS English
SigmaAldrich English
ALFA English
 
4,4'-Dichlorodiphenyl sulfone Usage And Synthesis
Chemical Properties off-white crystals or powder
Uses 4,4'Dichlorodiphenyl Sulfone is an impurity of Dapson (D193250), an antibacterial used in the treatment of dermatitis herpetiformis.
Uses Bis(4-chlorophenyl) sulfone is used as a precursor to prepare 4,4'-diamino-diphenyl sulfone and polysulfone plastics. It is also used to prepare rigid and temperature resistant polymers such as PES or Udel through polymerization with bisphenol-A and bisphenol-S. Further, the udel polymer finds applications in plumbing pipes, printer cartridges and automobile fuses.
General Description Crystals or off-white powder.
Air & Water Reactions Insoluble in water.
Reactivity Profile 4,4'-Dichlorodiphenyl sulfone is incompatible with strong oxidizers.
Fire Hazard Flash point data for 4,4'-Dichlorodiphenyl sulfone are not available; however, 4,4'-Dichlorodiphenyl sulfone is probably combustible.
Flammability and Explosibility Non flammable
Safety Profile Mildly toxic by ingestion. When heated to decomposition it emitsvery toxic fumes of Cl- and SOx.
 
4,4'-Dichlorodiphenyl sulfone Preparation Products And Raw materials
Raw materials Aluminum chloride-->Chlorobenzene
Preparation Products 4-[(4-Chlorophenyl)sulfonyl]benzoic acid-->Bis[4-(4-aminophenoxy)phenyl]sulfone-->Sulfenone-->bis(4-chloro-3-nitrophenyl) sulphone-->4,4'-Diaminodiphenylsulfone

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