2-(2-Aminoethylamino)ethanol

2-(2-Aminoethylamino)ethanol

Product Introduction

2-(2-Aminoethylamino)ethanol Basic information
Product Name: 2-(2-Aminoethylamino)ethanol
Synonyms: 2-(2-AMINOETHYLAMINO)ETHANOL;AMINOETHYLETHANOLAMIN;AMINOETHYLETHANOLAMINE;AMINOETHYETHANOLAMINE;AEEA;HYDROXYETHYL-ETHYLENEDIAMINE;LABOTEST-BB LTBB000455;N-HYDROXYETHYL-1,2-ETHANEDIAMINE
CAS: 111-41-1
MF: C4H12N2O
MW: 104.15
EINECS: 203-867-5
Product Categories: organic synthesis and intermediates;Organics;111-41-1
Mol File: 111-41-1.mol
2-(2-Aminoethylamino)ethanol Structure
 
2-(2-Aminoethylamino)ethanol Chemical Properties
Melting point -28 °C
Boiling point 238-240 °C/752 mmHg (lit.)
density 1.03 g/mL at 25 °C (lit.)
vapor density 3.6 (vs air)
vapor pressure <0.01 hPa (20 °C)
refractive index n20/D 1.485(lit.)
Fp >230 °F
storage temp. Store below +30°C.
solubility soluble
pka pK1:7.21(+2);pK2:10.12(+1) (25°C)
form Liquid
color Clear Colorless
Odor mild ammoniacal odor
PH 11.8 (111g/l, H2O, 20℃)
explosive limit 3.3-10.1%(V)
Water Solubility soluble
Sensitive Hygroscopic
BRN 506012
Dielectric constant 18.989999999999998
Exposure limits NIOSH: TWA 0.1 mg/m3
InChIKey LHIJANUOQQMGNT-UHFFFAOYSA-N
LogP -2.2--1.46 at 20-25℃ and pH7-11
Surface tension 67.11mN/m at 1g/L and 20℃
Dissociation constant 6.83-9.82 at 25℃
CAS DataBase Reference 111-41-1(CAS DataBase Reference)
NIST Chemistry Reference Ethanol, 2-[(2-aminoethyl)amino]-(111-41-1)
EPA Substance Registry System N-Hydroxyethylethylenediamine (111-41-1)
 
Safety Information
Hazard Codes C,T
Risk Statements 34-43-61-62
Safety Statements 26-36/37/39-45-53-28A
RIDADR UN 2735 8/PG 2
WGK Germany 1
RTECS KJ6300000
Autoignition Temperature 345 °C
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29221980
Hazardous Substances Data 111-41-1(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 3000 mg/kg LD50 dermal Rabbit > 2000 mg/kg
 
MSDS Information
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2-(2-Aminoethylamino)ethanol English
SigmaAldrich English
ACROS English
ALFA English
 
2-(2-Aminoethylamino)ethanol Usage And Synthesis
Description Aminoethylethanolamine is a component of colophony in soldering flux, which may cause contact and airborne contact dermatitis in workers in the electronic industry or in cable jointers.
Chemical Properties Aminoethylethanolamine is combustible, colorless, liquid with an ammonia-like odor.
Chemical Properties CLEAR VISCOUS LIQUID
Uses Textile finishing compounds (antifuming agents, dyestuffs, cationic surfactants), resins, rubber products, insecticides, and certain medicinals.
Uses It is used as an important intermediate in the manufacture of lube oil additives, fuel additives, chelating agents, surfactants and fabric softeners among other applications. N-(2-Hydroxyethyl)ethylenediamine [N-(2-Aminoethyl)ethanolamine] is used to study the aerobic biodecomposition of amines in hypersaline wastewaters.
Uses N-(2-hydroxyethyl)ethylenediamine (hydeten) or [N-(2-aminoethyl)ethanolamine] can be used as:

A precursor in the synthesis of room-temperature ionic liquids, acetate and formate ammonium salts of N-(2-hydroxyethyl)-ethylenediamine.

A ligand in the preparation of polymeric cyano-bridged platinum(II)complexes, ligand-copper(II)carbohydrate complexes and cyano-bridged Ni-Pt and Cu-Pt coordination polymers.


It can also be used to study the aerobic biodecomposition of amines in hypersaline wastewaters.
General Description A clear colorless liquid with an ammonia-like odor. Corrosive to tissue. Combustible, but may be difficult to ignite. Less dense than water. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion. Used to make other chemicals.
Air & Water Reactions Water soluble. Hygroscopic.
Reactivity Profile 2-(2-Aminoethylamino)ethanol is an amine and alcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. 2-(2-Aminoethylamino)ethanol is hygroscopic.
Health Hazard Skin contact will cause mild irritation; eye contact will cause more severe irritation.
Fire Hazard 2-(2-Aminoethylamino)ethanol is combustible.
Contact allergens Aminoethylethanolamine is a component of colophony in soldering flux, which may cause contact and airborne contact dermatitis in workers in the electronic industry or cable jointers.
Potential Exposure Used to make textile finishing compounds, dyes, resins, rubber, insecticides, medicines, and oth
Shipping UN2735 Amines, liquid, corrosive, n.o.s, or Polyamines, liquid, corrosive, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.
Purification Methods Distil the amine twice through a Vigreux column (p 11). Redistil it from solid NaOH, then from CaH2. Alternatively, it can be converted to the dihydrochloride and recrystallised from water. It is then dried, mixed with excess of solid NaOH and the free base is distilled from the mixture. It is finally redistilled from CaH2. [Drinkard et al. J Am Chem Soc 82 2992 1960, Beilstein 4 IV 1558.]
Incompatibilities Contact with cellulose nitrate may cause fires upon contact. Reacts with Oxidizers, strong acids.
 
2-(2-Aminoethylamino)ethanol Preparation Products And Raw materials
Raw materials Ethylenediamine
Preparation Products Silk softener L-->cocoyl coarboxy methyl imidazoline acetat XCG-CA-2 type-->laurylamide propionate JHZ-101-->lauroamphopropyl sulfonate-->castor oil type amphoteric surfactant JHZ-103-->N,N'-Dimethylpiperazine-->1,4-DIETHYLPIPERAZINE-->PIPERAZINE DIHYDROCHLORIDE-->1-(2-Hydroxyethyl)-2-imidazolidinone-->1-(2-Aminoethyl)imidazolidin-2-one-->N-Methyl-N-(N,N-dimethylaminoethyl)-aminoethanol-->2,2,2-TRIFLUORO-N-(2-(2-HYDROXYETHYLAMINO)ETHYL)ACETAMIDE-->tert-Butyl (2-((tert-butoxycarbonyl)amino)ethyl)(2-hydroxyethyl)carbamate

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