N-Hendecane

N-Hendecane

Product Introduction

n-Hendecane Basic information
Product Name: n-Hendecane
Synonyms: HENDECANE;ALKANE C11;Undecane [Standard Material];UNDECANE;hendecane(undecane);n-C11H24;undecanenormal;N-HENDECANE
CAS: 1120-21-4
MF: C11H24
MW: 156.31
EINECS: 214-300-6
Product Categories: n-Paraffins (GC Standard);Standard Materials for GC;Analytical Chemistry
Mol File: 1120-21-4.mol
n-Hendecane Structure
 
n-Hendecane Chemical Properties
Melting point -26 °C (lit.)
Boiling point 196 °C (lit.)
density 0.74 g/mL at 25 °C (lit.)
vapor density 5.4 (vs air)
vapor pressure <0.4 mm Hg ( 20 °C)
refractive index n20/D 1.417(lit.)
Fp 140 °F
storage temp. Store below +30°C.
form Liquid
color Colorless
Specific Gravity 0.7402
Odor Threshold 0.62ppm
explosive limit 0.6-6.5%(V)
Water Solubility IMMISCIBLE
BRN 1697099
Dielectric constant 2.0(20℃)
InChIKey RSJKGSCJYJTIGS-UHFFFAOYSA-N
LogP 6.312 (est)
CAS DataBase Reference 1120-21-4(CAS DataBase Reference)
NIST Chemistry Reference Undecane(1120-21-4)
EPA Substance Registry System Undecane (1120-21-4)
 
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-65-66
Safety Statements 26-36-24/25-62
RIDADR UN 2330 3/PG 3
WGK Germany 3
RTECS YQ1525000
Autoignition Temperature 220 °C
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29011090
Hazardous Substances Data 1120-21-4(Hazardous Substances Data)
Toxicity mouse,LD50,intravenous,517mg/kg (517mg/kg),Journal of Pharmaceutical Sciences. Vol. 67, Pg. 566, 1978.
 
MSDS Information
Provider Language
n-Hendecane English
SigmaAldrich English
ACROS English
ALFA English
 
n-Hendecane Usage And Synthesis
Chemical Properties colourless liquid.
Uses Petroleum research, organic synthesis, distillation chaser.
Uses Undecane is used in preparation method of small-size hollow Silicon Dioxide.
Uses Undecane is mainly used as a model n-alkane in studies relating to viscosities, excess molar enthalpies and vapor-liquid equilibrium of binary alkane mixtures.
Definition ChEBI: Undecane is a straight-chain alkane with 11 carbon atoms.
Production Methods Undecane is obtained from the refining of petroleum. Paraffins are isolated by selective adsorption followed by fractional distillation to produce the desired mix of nparaffins (63).
Synthesis Reference(s) Journal of the American Chemical Society, 95, p. 6131, 1973 DOI: 10.1021/ja00799a058
The Journal of Organic Chemistry, 50, p. 3082, 1985
General Description A colorless liquid. Insoluble in water and less dense than water. Flash point 130°F. Used to make other chemicals.
Air & Water Reactions Flammable. Insoluble in water.
Reactivity Profile Saturated aliphatic hydrocarbons, such as n-Hendecane, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents.
Health Hazard Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Safety Profile Moderately toxic by intravenous route. Flammable liquid when exposed to heat, sparks, flame, or oxidizers.To fight fire, use foam, mist, dry chemical. Emitted from modern buildmg materials (CENEAR 69,22,91). When heated to decomposition it emits acrid smoke and irritating fumes. See also ALKANES.
Carcinogenicity Undecane (25 mg) and benzo[a] pyrene (B[a]P) (5 mg) were applied to the skin of female ICR/ Ha Swiss mice for 3/week for 440 days, inducing papillomas in 41 of 50 animals. B[a]P alone induced tumors in 12 of 50 animals in the same time, while undecane alone did not produce tumors.
 
n-Hendecane Preparation Products And Raw materials
Raw materials 8-Heptadecene, (8E)--->N-UNDECYLCYCLOHEXANE-->Cuscohygrine-->2-METHYLTETRADECANE-->6-UNDECANOL-->N-PENTADECANE
Preparation Products 2-Pentyl-3-methyl-2-cyclopenten-1-one-->ETHYL UNDECANOATE-->N-NONANE

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