Ethyl 1,1,2,2-tetrafluoroethyl Ether

Ethyl 1,1,2,2-tetrafluoroethyl Ether

Product Introduction

Ethyl 1,1,2,2-tetrafluoroethyl ether Basic information
Product Name: Ethyl 1,1,2,2-tetrafluoroethyl ether
Synonyms: ether,ethyl1,1,2,2-tetrafluoroethyl;1,1,2,2-Tetrafluoro ethyl ether;3-Oxa-1,1,2,2-tetrafluoropentane, 1-Ethoxy-1,1,2,2-tetrafluoroethane;Ethane,1-ethoxy-1,1,2,2-tetrafluoro-;HYDROFLUOROETHER(HFE-374);1-ethoxy-1,1,2,2-tetrafluoro-ethan;1-ethoxy-1,1,2,2-tetrafluoroethane;374pcebetagamma
CAS: 512-51-6
MF: C4H6F4O
MW: 146.08
EINECS:  
Product Categories:  
Mol File: 512-51-6.mol
Ethyl 1,1,2,2-tetrafluoroethyl ether Structure
 
Ethyl 1,1,2,2-tetrafluoroethyl ether Chemical Properties
Boiling point 57 °C
density 1.198
refractive index 1.294
Fp 56-58°C
form clear liquid
Specific Gravity 1.198
color Colorless to Almost colorless
CAS DataBase Reference 512-51-6(CAS DataBase Reference)
EPA Substance Registry System Ethane, 1-ethoxy-1,1,2,2-tetrafluoro- (512-51-6)
 
Safety Information
Hazard Codes F,Xi
Risk Statements 11
Safety Statements 16-23-33
RIDADR 3271
RTECS KI3590000
Hazard Note Flammable
HazardClass 3
PackingGroup II
HS Code 2909199090
Toxicity LC inhalation in rat: > 30000ppm/4H
 
MSDS Information
Provider Language
ALFA English
 
Ethyl 1,1,2,2-tetrafluoroethyl ether Usage And Synthesis
Description Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a fluorinated linear ether with several fundamental properties that make it useful in batteries. First, ETFE is miscible with many polar organic solvents used in electrolyte formulations, which improves the ionic conductivity of the battery. Additionally, ETFE has a relatively low viscosity (486 mPa?s at 23 °C) and a low boiling point (58 °C), which make it a versatile diluent for low-temperature applications.
Uses Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a highly effective additive in lithium-ion and sodium-ion batteries for improving battery performance, increasing safety, and reducing flammability. ETFE is a versatile co-solvent with high miscibility, which allows it to be blended with other solvents to achieve high ionic conductivities. It is also a good SEI-forming electrolyte additive, stabilizing the Na electrode surface and enhancing the stability of high-voltage batteries. ETFE is particularly useful as an electrolyte co-solvent in lithium-sulfur (Li-S) batteries. Studies have shown that ETFE-containing electrolytes improve the stability of the electrolyte/anode interface and enhance the cycling, rate, and self-discharging of the Li-S cell more than glyme-based cosolvents or unblended solvents.
 
Ethyl 1,1,2,2-tetrafluoroethyl ether Preparation Products And Raw materials
Raw materials 1-CHLORO-1,1,2,2-TETRAFLUOROETHANE-->Sodium ethoxide-->Ethanol-->Tetrafluoroethylene

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