Hexamethylene Diacrylate

Hexamethylene Diacrylate

Product Introduction

Hexamethylene diacrylate Basic information
Description Sources
Product Name: Hexamethylene diacrylate
Synonyms: HDODA;HEXAMETHYLENE GLYCOL DIACRYLATE;Zinc02019846;1,6-BIS(ACRYLOYLOXY)HEXANE;1,6-HEXANEDIOL DIACRYLATE;1,6-HEXAMETHYLENE DIACRYLATE;Bisacrylic acid 1,6-hexanediyl ester;Bispropenoic acid 1,6-hexanediyl ester
CAS: 13048-33-4
MF: C12H18O4
MW: 226.27
EINECS: 235-921-9
Product Categories: Industrial/Fine Chemicals;Diacrylates & Dimethacrylates;monomer;Functional Materials;Reagent for High-Performance Polymer Research
Mol File: 13048-33-4.mol
Hexamethylene diacrylate Structure
 
Hexamethylene diacrylate Chemical Properties
Melting point 6°C
Boiling point 295°C
density 1.01 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
vapor pressure <0.01 mm Hg ( 20 °C)
refractive index n20/D 1.456(lit.)
Fp >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
solubility Chlroform (Slightly), DMSO (Slightly)
form Liquid
color Colourless
Specific Gravity 1.01
Water Solubility Slightly miscible with water.
Sensitive Hygroscopic
Stability: Light Sensitive
InChIKey FIHBHSQYSYVZQE-UHFFFAOYSA-N
LogP 2.81 at 25℃
CAS DataBase Reference 13048-33-4(CAS DataBase Reference)
NIST Chemistry Reference Hexamethylene diacrylate(13048-33-4)
EPA Substance Registry System 1,6-Hexanediol diacrylate (13048-33-4)
 
Safety Information
Hazard Codes Xi
Risk Statements 36/38-43
Safety Statements 39
RIDADR UN 3082 9/PG 3
WGK Germany 2
RTECS AT1430000
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 29161290
Hazardous Substances Data 13048-33-4(Hazardous Substances Data)
 
MSDS Information
Provider Language
Hexane-1,6-diyl bisacrylate English
SigmaAldrich English
ALFA English
 
Hexamethylene diacrylate Usage And Synthesis
Description Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more1. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides2-3.
Sources

https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf

Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.

https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf

Description Sensitizaion occurred after accidental occupational exposure in an employee in the laboratory of a plastic paint factory.
Chemical Properties Colorless transparent liquid
Uses 1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.
Uses 1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.
General Description Clear yellow liquid.
Air & Water Reactions Insoluble in water.
Reactivity Profile Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.
Fire Hazard Hexamethylene diacrylate is probably combustible.
Flammability and Explosibility Non flammable
 
Hexamethylene diacrylate Preparation Products And Raw materials
Raw materials 6-hydroxyhexyl acrylate-->acrylic acid methyl ester-->1,6-Hexanediol

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