TETRABUTYLPHOSPHONIUM HYDROXIDE

TETRABUTYLPHOSPHONIUM HYDROXIDE

Product Introduction

TETRABUTYLPHOSPHONIUM HYDROXIDE Basic information
Product Name: TETRABUTYLPHOSPHONIUM HYDROXIDE
Synonyms: TBPH;Tetrabutyl phosphorous hydroxide;TETRABUTYLPHOSPHONIUM HYDROXIDE;TETRA-N-BUTYLPHOSPHONIUM HYDROXIDE;TETRABUTYLPHOSPHONIUM HYDROXIDE SOL., 40% IN WATER;TETRABUTYLPHOSPHONIUM HYDROXIDE, 40 WT. % SOLUTION IN WATER;40%w/waqueoussolution;tetrabutylphosphonium hydroxide solution
CAS: 14518-69-5
MF: C16H37OP
MW: 276.44
EINECS: 238-528-0
Product Categories: Phosphonium Compounds
Mol File: 14518-69-5.mol
TETRABUTYLPHOSPHONIUM HYDROXIDE Structure
 
TETRABUTYLPHOSPHONIUM HYDROXIDE Chemical Properties
density 0.989 g/mL at 25 °C
refractive index n20/D 1.412
form Liquid
Specific Gravity 0.989
color Clear colorless to slightly yellow
Water Solubility Miscible with water.
Hydrolytic Sensitivity 0: forms stable aqueous solutions
BRN 4826225
CAS DataBase Reference 14518-69-5(CAS DataBase Reference)
EPA Substance Registry System Phosphonium, tetrabutyl-, hydroxide (1:1) (14518-69-5)
 
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3267 8/PG 2
WGK Germany -
F 10-34
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29319019
 
MSDS Information
Provider Language
SigmaAldrich English
ALFA English
 
TETRABUTYLPHOSPHONIUM HYDROXIDE Usage And Synthesis
Uses Tetrabutylphosphonium Hydroxide (TBPH) is a quaternary phosphonium salt. It is an effective catalyst in a variety of reactions. It is a strong base that can be used as a strong organic base catalyst. Its basicity combined with its function as phase transfer catalyst makes it a versatile catalyst in many biphasic organic transitions used in the manufacture of polymers, pharmaceuticals, agrochemicals, flavors and fragrances. Also it finds use as (trans)esterification catalyst for the preparation of several monomers,polymers and a cleaning agent for printed circuit boards and semiconductor wafers.
Applications:

Glycidyl Ether Intermediates used in pharmaceutical applications.

Chemicals for Polymer Applications.

Uses Tetrabutylphosphonium Hydroxide is a phase transfer catalyst for the etherification of thiosalicylic acid and analogs. Tetrabutylphosphonium Hydroxide is a pretreatment for rice husks that enhances enzymic and acid hydrolysis yields. Tetrabutylphosphonium Hydroxide is used in the synthesis of tetrabutylphosphonium carboxylate as a recyclable and highly selective catalysts for alcoholysis reaction of propylene oxide.

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